160 Halogenated Solvents
POTENTIAL HAZARDS
HEALTH
- Vapors may cause dizziness or suffocation.
- Exposure in an enclosed area may be very harmful.
- Contact may irritate or burn skin and eyes.
- Fire may produce irritating and/or toxic gases.
- Runoff from fire control or dilution water may cause pollution.
FIRE OR EXPLOSION
- Some of these materials may burn, but none ignite readily.
- Most vapors are heavier than air.
- Air/vapor mixtures may explode when ignited.
- Container may explode in heat of fire.
PUBLIC SAFETY
- CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
- Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160 feet) in all directions.
- Keep unauthorized personnel away.
- Stay upwind.
- Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks).
- Keep out of low areas.
- Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Structural firefighters' protective clothing will only provide limited protection.
EVACUATION
Large Spill
- Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
- If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
EMERGENCY RESPONSE
FIRE
Small Fires
- Dry chemical, CO2 or water spray.
Large Fires
- Dry chemical, CO2, alcohol-resistant foam or water spray.
- Move containers from fire area if you can do it without risk.
- Dike fire control water for later disposal; do not scatter the material.
Fire involving Tanks or Car/Trailer Loads
- Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
- Cool containers with flooding quantities of water until well after fire is out.
- Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
- ALWAYS stay away from tanks engulfed in fire.
SPILL OR LEAK
- ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
- Stop leak if you can do it without risk.
Small Liquid Spills
- Take up with sand, earth or other noncombustible absorbent material.
Large Spills
- Dike far ahead of liquid spill for later disposal.
- Prevent entry into waterways, sewers, basements or confined areas.
FIRST AID
- Move victim to fresh air.
- Call 911 or emergency medical service.
- Apply artificial respiration if victim is not breathing.
- Administer oxygen if breathing is difficult.
- Remove and isolate contaminated clothing and shoes.
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
- For minor skin contact, avoid spreading material on unaffected skin.
- Wash skin with soap and water.
- Keep victim warm and quiet.
- Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.