140 Oxidizers
POTENTIAL HAZARDS
FIRE OR EXPLOSION
- These substances will accelerate burning when involved in a fire.
- Some may decompose explosively when heated or involved in a fire.
- May explode from heat or contamination.
- Some will react explosively with hydrocarbons (fuels).
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Containers may explode when heated.
- Runoff may create fire or explosion hazard.
HEALTH
- Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns, or death.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may cause pollution.
PUBLIC SAFETY
- CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
- Isolate spill or leak area immediately for at least 10 to 25 meters (30 to 80 feet) in all directions.
- Keep unauthorized personnel away.
- Stay upwind.
- Keep out of low areas.
- Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
- Wear positive pressure self-contained breathing apparatus (SCBA).
- Structural firefighters' protective clothing will only provide limited protection.
EVACUATION
Large Spill
- Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
- If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
EMERGENCY RESPONSE
FIRE
Small Fires
- Use water. Do not use dry chemicals or foams. CO2 or Halon may provide limited control.
Large Fires
- Flood fire area with water from a distance.
- Move containers from fire area if you can do it without risk.
- Do not move cargo or vehicle if cargo has been exposed to heat.
- Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
- Cool containers with flooding quantities of water until well after fire is out.
- ALWAYS stay away from tanks engulfed in fire.
- For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
- Keep combustibles (wood, paper, oil, etc.) away from spilled material.
- Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
- Stop leak if you can do it without risk.
- Do not get water inside containers.
Small Dry Spills
- With clean shovel place material
into clean, dry container and cover loosely;
move containers from spill area.
Small Liquid Spills
- Use a non-combustible material
like vermiculite, sand or earth to soak up
the product and place into a container for later disposal.
Large Spills
- Dike far ahead of liquid spill for later disposal.
- Following product recovery, flush area with water.
- With clean shovel place material
into clean, dry container and cover loosely;
move containers from spill area.
FIRST AID
- Move victim to fresh air.
- Call 911 or emergency medical service.
- Apply artificial respiration if victim is not breathing.
- Administer oxygen if breathing is difficult.
- Remove and isolate contaminated clothing and shoes.
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
- Keep victim warm and quiet.
- Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.